Evidence for the synthesis of an unusual high spin (S = 7/2) [Cu-3Fe-4S] cluster in the radical-SAM enzyme RSAD2 (viperin)

K. Honarmand Ebrahimi, C. Silveira, S. Todorovic

Research output: Contribution to journalArticlepeer-review

4 Citations (Scopus)

Abstract

We demonstrate the synthesis and spectroscopic characterization of an unusual high spin (S = 7/2) [Cu-3Fe-4S] cluster in a member of the radical-SAM enzymes. This is the first step in using synthetic [Me-3Fe-4S] clusters for obtaining new insight into the mechanism of radical-SAM catalysis.

Original languageEnglish
Pages (from-to)8614-8617
Number of pages4
JournalChemical Communications
Volume54
Issue number62
DOIs
Publication statusPublished - 1 Jan 2018

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