Raman spectroscopic study of the vapor phase of l-Methylimidazolium ethanoate, a protic ionic liquid

Luis Paulo Rebelo

doi:10.1021/jp1050639

Raman spectroscopic study of the vapor phase of l-Methylimidazolium ethanoate, a protic ionic liquid

Luis Paulo Rebelo

Instituto de Tecnologia Química e Biológica António Xavier (ITQB)

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

The gas phase over the ionic liquid l-methylimidazolium eihanoate, [Hmim][O2CCH3] was studied by means of Raman spectroscopy. Raman spectra are presented, the species in the gas phase;Ire identified, and their bands arc assigned. The results;ire interpreted using ab initio quantum mechanical calculations that also predict vibrational spectra. The obtained data reinforce a previous interpretation, based on FT-ICR mass spectrometric data, that the vapor phase over [Hmim][O2CCH3] consists predominantly of two neutral molecules, monomeric ethanoic acid and 1-methylimidazole.

Original language	Unknown
Pages (from-to)	10834-10841
Journal	Journal of Physical Chemistry A
Volume	114
Issue number	40
DOIs	https://doi.org/10.1021/jp1050639
Publication status	Published - 1 Jan 2010

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10.1021/jp1050639

Cite this

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title = "Raman spectroscopic study of the vapor phase of l-Methylimidazolium ethanoate, a protic ionic liquid",

abstract = "The gas phase over the ionic liquid l-methylimidazolium eihanoate, [Hmim][O2CCH3] was studied by means of Raman spectroscopy. Raman spectra are presented, the species in the gas phase;Ire identified, and their bands arc assigned. The results;ire interpreted using ab initio quantum mechanical calculations that also predict vibrational spectra. The obtained data reinforce a previous interpretation, based on FT-ICR mass spectrometric data, that the vapor phase over [Hmim][O2CCH3] consists predominantly of two neutral molecules, monomeric ethanoic acid and 1-methylimidazole.",

keywords = "GAS-PHASE",

author = "Rebelo, {Luis Paulo}",

note = "Canongia Lopes, Jose N., Ferreira Rui",

year = "2010",

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doi = "10.1021/jp1050639",

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pages = "10834--10841",

journal = "Journal Of Physical Chemistry A",

issn = "1089-5639",

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T1 - Raman spectroscopic study of the vapor phase of l-Methylimidazolium ethanoate, a protic ionic liquid

AU - Rebelo, Luis Paulo

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PY - 2010/1/1

Y1 - 2010/1/1

N2 - The gas phase over the ionic liquid l-methylimidazolium eihanoate, [Hmim][O2CCH3] was studied by means of Raman spectroscopy. Raman spectra are presented, the species in the gas phase;Ire identified, and their bands arc assigned. The results;ire interpreted using ab initio quantum mechanical calculations that also predict vibrational spectra. The obtained data reinforce a previous interpretation, based on FT-ICR mass spectrometric data, that the vapor phase over [Hmim][O2CCH3] consists predominantly of two neutral molecules, monomeric ethanoic acid and 1-methylimidazole.

AB - The gas phase over the ionic liquid l-methylimidazolium eihanoate, [Hmim][O2CCH3] was studied by means of Raman spectroscopy. Raman spectra are presented, the species in the gas phase;Ire identified, and their bands arc assigned. The results;ire interpreted using ab initio quantum mechanical calculations that also predict vibrational spectra. The obtained data reinforce a previous interpretation, based on FT-ICR mass spectrometric data, that the vapor phase over [Hmim][O2CCH3] consists predominantly of two neutral molecules, monomeric ethanoic acid and 1-methylimidazole.

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EP - 10841

JO - Journal Of Physical Chemistry A

JF - Journal Of Physical Chemistry A

SN - 1089-5639

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